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Kameron Wyman

Dec 05, 2024

Please answer my chemistry question below which is abt finding heat of vaporization & normal boiling point?

The vapor pressure of nitrogen at various temperatures is provided in the table below. Using this data, calculate:
A) The heat of vaporization of nitrogen.
B) The normal boiling point of nitrogen.

Temperature (K) | Pressure (torr)
-----------------|----------------
65 | 130.5
70 | 289.5
75 | 570.8
80 | 1028
85 | 1718

Please provide a complete solution with detailed steps, not just the final answers.

2 Answers

A
Anonymous

Jan 15, 2025

The vapor pressure of nitrogen at several different temperatures is shown below. Use the data to find A) heat of vaporization & B) normal boiling point.

When the vapor pressure = atmospheric pressure, the liquid boils!

Standard atmospheric pressure = 760 torr

Temperature (K), Pressure (torr)

65 , 130.5

70 , 289.5

75 , 570.8

80 , 1028

85 , 1718

You need an equation for the graph of the data above, see web site below!

https://eee.uci.edu/programs/gchem/05MANPTgasVPliq...

ln P = (-1 Heat of vaporization ÷ R) (1/T) + C

R = 8.3145 J/(mole * °K)

T = temperature in °K

ln P = (-1 Heat of vaporization ÷ 8.3145) (1/T) + C

Use several values of T and P to determine the value of Heat of vaporization

ln 130.5 = (-1 Heat of vaporization ÷ 8.3145) (1/65) + C

C = ln 130.5 – (-1 Heat of vaporization ÷ 8.3145) (1/65)

ln 570.8 = (-1 Hv ÷ 8.3145) (1/75) + ln 130.5 – (-1 Hv ÷ 8.3145) (1/65)

Subtract ln 130.5 from both sides

ln 570.8 – ln 130.5 = (-1 Hv ÷ 8.3145) (1/75) – (-1 Hv ÷ 8.3145) (1/65)

ln 570.8 – ln 130.5 = Hv (-1 ÷ 8.3145) (1/75) – (-1 ÷ 8.3145)* (1/65)

ln 570.8 – ln 130.5 = ( Hv /8.3145) * [(-1/75) – (-1/65)]

(6.347 – 4.871) 8.3145 = Hv [(-1/75) – (-1/65)]

Hv = (1.476 * 8.3145) ÷ 0.00205

Hv = 5986.44

C = ln 130.5 – (-1 5986.44 ÷ 8.3145) (1/65)

C = ln 130.5 – (-11.077)

C = 15.95

Then use the equation to determine the Temperature when P = 760 torr

ln P = (-720) * (1/T) + 15.95

P = 760

ln 760 = (-720) * (1/T) + 15.95

ln 760 – 15.95 = (-720) * (1/T)

(ln 760 – 15.95) ÷ (-720) = (1/T)

T = 77.3 °K

http://en.wikipedia.org/wiki/Nitrogen

BP = 77.36 °K

WOW

A
Anonymous

Jan 21, 2025

This Site Might Help You.

RE:

Please answer my chemistry question below which is abt finding heat of vaporization & normal boiling point?

The vapor pressure of nitrogen at several different temperatures is shown below. Use the data to find A) heat of vaporization & B) normal boiling point.

Temperature (K), Pressure (torr)

65 , 130.5

70 , 289.5

75 , 570.8

80 , 1028

85 , 1718

*PLEASE GIVE ME THE COMPLETE SOLUTION & NOT JUST...

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