The ksp of Ba(IO3)2 at 25 is 6×10^10 . What is the molar solubility of Ba(IO3)2 ?
The solubility product constant (Ksp) of barium iodate, Ba(IO3)2, at 25°C is 6 × 10^10. What is the molar solubility of Ba(IO3)2 in water?
4 Answers
Feb 09, 2025
The balanced equation is:
Ba(IO3)2 <-> Ba2 + 2IO3
I….._………….0……..0
C…_………..+x……+2x
F…_………….x………2x
Once balanced, input information at equilibrium:
Ksp = [Ba][IO3]^2
6.0×10^-10 = (x)(2x)^2
6.0×10^-10 = 4x^3
x = 0.00053 M = 0.00053 mol/L
This value for x also equals the molar solubility (mol/L) of Ba(IO3)2.
Feb 09, 2025
Ksp = [Ba+2][IO3]^2
If x g-ions of Ba+2 are in solution, so are 2x g-ions of the iodate. Then
4x^3= 6×10^-10 or x^3=150x^-12. Then x=5.2×10^-4, which is the molar solubility of the salt.
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Ksp = [Ba^2+(aq)][CrO4^2-(aq)] = 2.1*10^-10 [CrO4^2-(aq)] = 2.1*10^-10 / [Ba^2+(aq)] Since BaCrO4 has very low solubility, we can assume that in 0.0015M Na2CrO4(aq), [CrO4^2-(aq)] = 0.0015 mol/litre. So, 1.5*10^-3 = 2.1*10^-10 /[Ba^2+(aq)] then, [Ba^2+(aq)] = 2.1*10^-10 / 1.5*10^-3 = 1.4*10^-7 mol/litre. On dissolving BaCrO4, 1 mole of BaCrO4 produces 1 mole of Ba^2+ ions Therefore, Solubility of BaCrO4 = 1.4*10^-7 mol/litre Since BaCrO4 has Mr = 253 Solubility = 253 * 1.4*10^-7 g/litre = 3.54*10^-5 g/litre.
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