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What are the oxidation numbers of the elements in the nitrite ion, NO2−?

What are the oxidation states of the elements in the nitrite ion (NO2−)? Specifically, how do we determine the oxidation number of nitrogen and the oxidation numbers of the oxygen atoms in this ion?

3 Answers

A
Anonymous

Jan 18, 2025

In order to get the oxidation number of each element, refer to the rules of assigning oxidation number.

First, the rule says that "O" oxygen always have a (-2) charge(except if peroxide), this means the "x" is the unknown charge of nitrogen.

x= charge of nitrogen

-2 = charge of oxygen

Simply multiply its charge into how many atoms of an elements is present.

1x= x is multiplied by 1 since there is only 1 nitrogen

[2(-2)] = the oxygen's charge of -2 is multiplied to 2 since there are 2 oxygen atoms

And since (NO2-) is a polyatmic ion with a charge of -1 , the oxidation numbers should all add up to (-) or (-1)

Represent each in the equation:

1x + [2(-2)] = -1

1x -4 = -1

1x = -1 + 4

x= +3

This means that nitrogen has an oxidation of +3, and oxygen is -2

There is an easy way to assign oxidation by the way, I just chose to demonstrate it algebraically to show how it's being solved.

M
May Hayes III

Feb 19, 2025

Charge on the polyatomic anion is -1, so the sum of the charges must be -1

Oxygen's oxidation # is -2. Since there are 2 oxygen atoms in the compound,

the product is -4. 3 must be the oxidation # of N, since 3+ -4 = -1.

nitrate's oxidation #'s for N and O2, respectively, are 3 and -2

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