Marcia Kertzmann
Jan 03, 2025
What wouldHow much work is done on the gas during each of the three segments? you like to ask?
In a thermodynamic process involving 100 mg of helium, we have three distinct segments to analyze:
- Process 1 is isochoric.
- Process 2 is isothermal.
- Process 3 is isobaric.
The parameters for each process are as follows:
- Pressure (in atm): Process 1 - 0.833, Process 2 - 4.16, Process 3 - 0.833
- Temperature (in °C): Process 1 - 133, Process 2 - 1760, Process 3 - 1760
- Volume (in cm³): Process 1 - 1000, Process 2 - 1000, Process 3 - 5000
Could you please determine how much work is done on the gas during each of the three segments? Additionally, how much heat energy is transferred to or from the gas during these processes?
2 Answers
Jan 17, 2025
If i get right you have the following changes
process 1: isochoric change from state 1 to state 2
process 2: isothermal change from state 2 to state 3
process 3: isobaric change from state 3 back to state1
Generally the work done on the gas is given by the integral:
W = - ∫ p dV from initial to final volume of the process
First process is isochoric, that means the volumes does not change. So the integral is zero and no work is done
W₁ = 0
Second process is isothermal. From Ideal gas law follows that
p∙V = n∙R∙T = constant
because n and T are constant.
Hence you may use either
p∙V = p₂∙V₂
or
p∙V = p₃∙V₃
to substitute p in the work integral.
W₂ = - ∫ p dV from V₂ to V₃
= - ∫ p₂∙V₂/V dV from V₂ to V₃
= - p₂∙V₂ ∙ ∫ 1/V dV from V₂ to V₃
= - p₂∙V₂ ∙ln( V₃/V₂ )
= - 4.16∙101325Pa ∙ 1×10⁻³m³ ∙ln( 5×10⁻³m³/1×10⁻³m³ )
= - 4.16∙101325Pa ∙ 1×10⁻³m³ ∙ln( 5×10⁻³m³/1×10⁻³m³ )
= -678.4J
(note: 1Pam³ = 1J)
Third process is isobaric, i.e
p = constant = p₃ = p₁
=>
W₃ = - ∫ p₁ dV from V₃ to V₁
= - p₁ ∙ ∫ dV from V₃ to V₁
= - p₁ ∙ (V₁ - V₃)
= p₁ ∙ (V₃ - V₁)
= 0.833∙101325Pa ∙ (5×10⁻³m³ - 1×10⁻³m³)
= 337.6J
To find the amount of heat transferred in each process, consider the change of internal energy. Change of internal energy equals heat transferred to the gas plus work done on it:
∆U = Q + W
Moreover the change of internal of an ideal gas is given by its change in temperature:
∆U = m∙Cv∙∆T
Hence:
Q = m∙Cv∙∆T - W
Mass specific heat capacity of Helium is
Cv = Cv,m / M = (3/2)∙R/M
= (3/2)∙8.314472J/molK / 4g/mol
= 3.118J/gK
Q₁ = m∙Cv∙(T₂ - T₁) - W₁
= 100×10⁻³g ∙ 3.118J/gK ∙ (1760 - 133)K - 0J
= 507.3J
Q₂ = m∙Cv∙(T₃ - T₂) - W₂
= 100×10⁻³g ∙ 3.118J/gK ∙ (1760 - 1760)K - (-678.4J)
= 678.4J
Q₃ = m∙Cv∙(T₁ - T₃) - W₃
= 100×10⁻³g ∙ 3.118J/gK ∙ (133 - 1760)K - 337.6J
= -844.9J
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